所屬系統：地球物質(zhì)成分與物質(zhì)性質(zhì)分析系統
實(shí)驗室位置：地3樓105、119
實(shí)驗室主任：王浩 副研究員
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實(shí)驗室概況 | 儀器介紹 | 實(shí)驗室成員 | 工作內容 | 用戶(hù)須知 | 收費須知 | 歡迎來(lái)訪(fǎng)
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MC-ICP-MS實(shí)驗室成立于2003年，主要運用激光剝蝕系統與電感耦合等離子體質(zhì)譜技術(shù)相結合開(kāi)展固體樣品的微區微量元素和同位素分析。針對地學(xué)領(lǐng)域的科學(xué)問(wèn)題，研發(fā)了一系列原位微區微量元素、U-Pb定年、Mg-Si-Ti-Fe-Zr穩定同位素以及Sr-Nd-Hf放射性同位素等分析方法和標準物質(zhì)，并將這些方法廣泛應用于巖漿動(dòng)力過(guò)程示蹤、沉積物源分析、變質(zhì)作用元素與同位素行為揭示、精細成礦記錄甄別、大陸地殼形成及造山帶演化等諸多研究領(lǐng)域。
實(shí)驗室保持高效、開(kāi)放、合作的工作模式，吸引了大批國內外知名學(xué)者來(lái)實(shí)驗室開(kāi)展分析與合作研究。近五年來(lái)，先后有澳大利亞、美國、英國、德國、印度、韓國、香港、臺灣等18個(gè)國家和地區的科學(xué)家來(lái)實(shí)驗室進(jìn)行合作研究，并取得了大量突出的成果。利用MC實(shí)驗室分析數據所發(fā)表的國內外SCI論文自2004年之來(lái)一直呈增加趨勢，使MC-ICP-MS實(shí)驗室逐步成為國際原位微區分析的重要基地，不僅提升了我國在該領(lǐng)域國際上的地位和影響，也為國內外地學(xué)科學(xué)家提供了一個(gè)良好的現代地球化學(xué)化學(xué)分析技術(shù)平臺。
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多接收-電感耦合等離子體質(zhì)譜儀的基本結構和原理：
1）進(jìn)樣系統：包括液體進(jìn)樣和固體進(jìn)樣兩種方式。液體樣品通過(guò)霧化器進(jìn)行霧化并送入電離源，固體樣品需經(jīng)過(guò)激光剝蝕后由載氣送入電離源；
2）電離源：用于實(shí)現樣品離子化的模塊。ICP（電感耦合等離子體）即為MC-ICP-MS的離子源，樣品被送入該模塊被電離成離子（具體原理參考附件中的“Plasma Source”)；
3）采樣錐和截取錐：離子源形成的等離子體炬處于常壓下,離子傳輸系統和質(zhì)量分析器分別需要低、高真空的環(huán)境。提取接口由采樣錐、截取錐及擴散室組成,實(shí)現了真空環(huán)境的過(guò)渡和等離子體氣流的提取。等離子體氣流在采樣錐口處德拜長(cháng)度約為10-5mm, 遠小于錐孔直徑, 因此等離子體通過(guò)采樣錐的過(guò)程可看作中性氣流的運動(dòng)。在真空壓差的作用下, 等離子體氣流在擴散室迅速膨脹為超聲射束。由于電子密度的下降速度較電子溫度快, 在截取錐孔處德拜長(cháng)度增大為 10-2 mm 數量級,但仍小于截取錐孔直徑, 因此氣流準中性的狀態(tài)延續到了截取錐后。隨后, 電子密度進(jìn)一步下降, 在提取透鏡的負電壓下出現電荷分離, 負電荷粒子被排斥, 形成正離子束。
4）離子透鏡系統：將離子束傳輸至ESA模塊（靜電分析器），通過(guò)透鏡組電壓參數的調整優(yōu)化，實(shí)現離子傳輸率最大化的同時(shí)，將離子束調整至最優(yōu)的形狀；
5）ESA（靜電分析器）：它的作用是實(shí)現離子束的能量聚焦，為后續磁式質(zhì)量分析器提供最佳的離子束入射狀態(tài)，以實(shí)現最佳的質(zhì)量分辨率；
6）離子狀態(tài)調諧透鏡系統：位于磁式質(zhì)量分析器的入口處和出口處，用于離子束形狀的調整和實(shí)現質(zhì)量分析器分析質(zhì)量范圍擴展；
7）磁式質(zhì)量分析器：整個(gè)儀器的核心，實(shí)現質(zhì)量分析。其原理就是不同質(zhì)量數的離子在磁場(chǎng)運動(dòng)中的偏轉半徑不一樣，從而實(shí)現不同質(zhì)量離子的分離。它是一種位置分辨的質(zhì)量分析器,區別于四級桿質(zhì)量分析器(7500a);
8）檢測器：經(jīng)過(guò)磁式質(zhì)量分析器分離的不同質(zhì)量的離子被檢測器檢測從而輸出其對應質(zhì)量數的離子強度，實(shí)現半定量或定量分析。多接收的含義也就體現在檢測器上，即有多個(gè)檢測器同時(shí)檢測不同質(zhì)量數的離子。在本實(shí)驗室的MC-ICP-MS上配有9個(gè)檢測器（法拉第杯），也即能夠同時(shí)檢測9個(gè)不同質(zhì)量數的離子。
2. 實(shí)驗室儀器：?
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美國Thermo Scientific公司，型號為Neptune Plus的MC-ICP-MS，雙聚焦磁式質(zhì)譜儀。 |
美國Thermo Scientific公司，型號為Neptune的MC-ICP-MS， 雙聚焦磁式質(zhì)譜儀。 |
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美國Thermo Scientific公司，型號為Element XR的HR-ICP-MS，高分辨磁式質(zhì)譜儀。 |
美國Thermo Scientific公司，型號為iCAP TQ的ICP-Q-MS/MS，三重四極桿質(zhì)譜儀。 |
美國Agilent公司，型號為7500a的Q-ICP-MS，四級桿質(zhì)譜儀。 |
Coherent公司，型號為COMPex Pro的193nm激光剝蝕系統，準分子氣體激光器。 |
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Photon-machines公司，型號為Analyte G2的193nm激光剝蝕系統，準分子氣體激光器。 |
美國Elemental Scientific Lasers公司，型號為NWRFemto UC (DW)的雙波長(cháng)飛秒激光剝蝕系統（257nm和1030nm）。 |
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王浩：實(shí)驗室主任，副研究員。主要研究方向：變質(zhì)巖年代學(xué)、巖漿巖地球化學(xué)、前寒武紀地質(zhì)學(xué)。主要研究包括利用地球化學(xué)數據解譯造山過(guò)程的變質(zhì)記錄與地殼演化，地球早期分異以及板塊構造啟動(dòng)等過(guò)程。負責實(shí)驗室研究方向的把握和實(shí)驗室管理。 Email:wanghao@mail.iggcas.ac.cn |
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謝烈文：正高級工程師。主要從事ICP-MS和MC-ICP-MS儀器維護、分析技術(shù)方法研發(fā)和巖石地球化學(xué)研究工作。曾先后研發(fā)鋯石原位微區Hf同位素、鋯石原位微區U-Pb、Hf同位素和微量元素聯(lián)機分析方法，在國內外重要刊物上已發(fā)表30余篇論文。 Email：xieliewen@mail.iggcas.ac.cn |
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楊岳衡：正高級工程師，國家杰出青年科學(xué)基金獲得者，刷卡系統儀器操作員。主要從事同位素地球化學(xué)研究。負責原位Sr-Nd同位素測試及質(zhì)量監控工作，在國內外重要刊物上發(fā)表SCI論文10余篇。 Email：yangyueheng@mail.iggcas.ac.cn |
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黃超：高級工程師，精密儀器專(zhuān)業(yè)，負責儀器的日常維護、維修及運行，參與儀器及分析新方法的研究。 Email：huangchao@mail.iggcas.ac.cn |
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吳石頭: 高級工程師, 主要從事SF-ICP-MS分析方法開(kāi)發(fā)和微量元素地球化學(xué)研究, 負責LA-ICPMS鋯石（其他副礦物）U-Pb定年，單礦物微區微量元素分析，溶液全巖微量元素分析。在國內外重要刊物上已發(fā)表16篇論文。 Email:shitou.wu@mail.iggcas.ac.cn |
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許蕾：工程師，主要從事同位素地球化學(xué)研究。負責原位Fe-S同位素方法研發(fā)和質(zhì)量監控，實(shí)驗預約及實(shí)驗室收支費用等日常管理工作。 Email：leixu@mail.iggcas.ac.cn |
本實(shí)驗室主要進(jìn)行如下方面的分析測試工作（實(shí)驗室主要方法論著(zhù)及專(zhuān)利）：
1. 礦物激光微區U-Pb定年和元素分析
為了有效確定地質(zhì)體演化史，厘定自然界不同地質(zhì)單元的形成時(shí)代，實(shí)驗室在研制標樣的基礎上，先后開(kāi)發(fā)了鋯石、榍石、獨居石、磷釔礦、鈮鉭礦、氟碳鈰礦、石榴石、黑鎢礦、錫石、符山石、褐簾石和方解石等礦物的U-Pb激光微區測年和同時(shí)獲得多元素（>30種）含量信息的方法。這些方法為限定復雜地質(zhì)過(guò)程的時(shí)代和屬性提供了重要的研究工具，結合原位微區Sr-Nd-Hf同位素分析，可有效示蹤巖石源區、巖漿混合、地殼混染、變質(zhì)作用等復雜的地質(zhì)過(guò)程。
2. 礦物原位微區Sr-Nd-Hf同位素分析
Sr-Nd-Hf同位素是地球化學(xué)領(lǐng)域應用最廣的同位素體系。但一直以來(lái)，該同位素主要通過(guò)溶液法進(jìn)行測定，這不僅費時(shí)、耗力，而且不能得到微區的信息。通過(guò)細致的工作，MC-ICP-MS實(shí)驗室開(kāi)發(fā)出了單礦物激光原位Sr-Nd-Hf同位素分析技術(shù)，從而使本實(shí)驗室成為世界上最早能開(kāi)展此方法研究的實(shí)驗室之一。目前能夠測定的礦物包括斜長(cháng)石、方解石、單斜輝石、榍石、磷灰石、鈣鈦礦、獨居石、氟碳鈰礦、燒綠石、褐簾石、鋯石、斜鋯石、鈣鈦鋯石、鈦鋯釷礦、鈣鋯鈦礦、異性石、金紅石、鈮鐵礦和錫石等。特別是鈣鈦礦U-Pb年齡、微量元素和Sr-Nd同位素分析方法的建立，為解決金伯利巖的時(shí)代與成因難題提供了重要的研究工具。
3. 礦物微區Mg-Si-Ti-Fe-Zr非傳統穩定同位素分析
非傳統穩定同位素是近年來(lái)飛速發(fā)展的重要學(xué)科方向。高精度的溶液非傳統穩定同位素分析不僅揭示了不同地質(zhì)儲庫間的微小差異，還在示蹤表殼物質(zhì)再循環(huán)以及高溫巖漿和成礦過(guò)程等領(lǐng)域中發(fā)揮了重要作用。然而巖漿結晶、多階段變質(zhì)和流體活動(dòng)以及擴散作用等通常會(huì )引起礦物內部極大的同位素環(huán)帶，揭示這些過(guò)程需要精細的微區非傳統穩定同位素分析工作。MC-ICP-MS實(shí)驗室致力于開(kāi)發(fā)微區非傳統穩定同位素分析方法，目前已初步完成了針對橄欖石、石英、金紅石、鈦鐵礦、黃鐵礦和鋯石等礦物的微區Mg-Si-Ti-Fe-Zr等非傳統穩定同位素分析方法開(kāi)發(fā)，更多同位素體系的研究工作正在進(jìn)行中。
2023
1.?Wu?S, Wang H, Yang Y, Niu J, Lan Z, Zhang L, Huang C, Xie L, Xu L, Yang J, Wu F, 2023. In situ Lu-Hf geochronology with LA-ICP-MS/MS.?Journal of Analytical Atomic Spectrometry.?38, 1285-1300.?
2.?Wu S, Yang Y, Li T, Huang C, Bao Z, Li Y, Li C, Xu L, Wang H, Xie L, Yang J,?Wu F. 2023.?Calcite TLM and LSJ07– two natural low-Sr reference materials for microbeam Sr isotope analysis. Journal of Analytical Atomic Spectrometry. 38, 2528-2537.
3.?謝博航, 吳石頭*, 楊岳衡, 王浩, 趙子福, 黃超, 謝烈文. 2023. LA-MC-ICP-MS方解石U-Pb定年技術(shù). 巖石學(xué)報, 039(01): 0236-0248.
4.?Huang C, Chen J, Yang Y, Xie L, Wu S, Xu L, Wang H, Yang J. 2023. A new reference material for O–Sr isotope determination in epidote using a micro-beam.?Journal of Analytical Atomic Spectrometry.?38, 1592-1601.
5.?Huang C, Wang H, Shi W, Sun J, Hu F, Xu L Yang Y, Wu S, Xie L, Yang J. 2023. In situ Rb-Sr dating of mica by LA-ICP-MS/MS. Science China Earth Sciences.?66, 2603–2621.
6.?Yang Y, Chu Z, Wu S, Xie L, Huang C, Yang J, Wu F. 2023. Simultaneous Measurement of 147Sm/144Nd and 143Nd/144Nd Ratios in Natural Geological Samples by MC-ICP-MS After One Stage Chemical Purification Using TODGA Resin. Atomic Spectroscopy, 44, 247–252.?
2022
7.?Wei, Q. D., Yang, M., Romer, R. L., Wang, H., Yang, Y. H., Zhao, Z. F., & Wu, F. Y. 2022. In situ U–Pb geochronology of vesuvianite by LA-SF-ICP-MS. Journal of Analytical Atomic Spectrometry, 37(1), 69-81.
8.?Yang, M., Romer, R. L., Yang, Y. H., Wu, S. T., Wang, H., Tu, J. R., Zhou, H., Y., Xie. L. W., Huang C., Xu L., Yang J. H., and Wu, F. Y. 2022. U-Pb isotopic dating of cassiterite: Development of reference materials and in situ applications by LA-SF-ICP-MS.?Chemical Geology,?593, 120754.
9.?Yang, M., Yang, Y. H., Kamo, S. L., Romer, R. L., Roberts, N. M., Wang, H., Xie L., W., Huang C., Yang J., H., & Wu, F. Y. 2022. Natural Allanite Reference Materials for In Situ U-Th-Pb and Sm-Nd Isotopic Measurements by LA-(MC)-ICP-MS.?Geostandards and Geoanalytical Research, 46(2), 169-203.
10.?Wu, S., Yang, Y., Roberts, N. M., Yang, M., Wang, H., Lan, Z., & Wu, F. 2022. In situ calcite U-Pb geochronology by high-sensitivity single-collector LA-SF-ICP-MS. Science China Earth Sciences, 65(6), 1146-1160.
11.?Wu, S., Audétat, A., Jochum, K. P., Wang, H., Chen, J., Stoll, B., & Yang, J. 2022. Three Natural Andesitic to Rhyolitic Glasses (OJY‐1, OH‐1, OA‐1) as Reference Materials for In Situ Microanalysis. Geostandards and Geoanalytical Research, 46, 673-700.
12.?Xu, L., Yang, J. H., Xie, L. W., Wang, H., Yang, Y. H., Huang, C., & Wu, S. T. 2022. Evaluation of plasma condition, concentration effect, position effect, and nickel-doping method on non-matrix-matched Fe isotopic analysis by femtosecond laser ablation multi-collector inductively coupled plasma mass spectrometry. Spectrochimica Acta Part B: Atomic Spectroscopy, 189, 106374.
13.?Xu, L., Yang, J. H., Wang, H., Li, Y., Zhou, B. Q., Yang, Y. H., & Wu, S. T. 2022. A natural plagioclase reference material for microbeam Sr isotopic analysis. Journal of Analytical Atomic Spectrometry, 37(8), 1706-1714.
14.?Xu, L., Yang, J. H., Wang, H., Xie, L. W., Yang, Y. H., Huang, C., & Wu, S. T. 2022. Analytical feasibility of a new reference material (IRMM-524A Fe metal) for the in situ Fe isotopic analysis of pyrite and ilmenite without matrix effects by femtosecond LA-MC-ICP-MS.?Journal of Analytical Atomic Spectrometry,?37(9), 1835-1845.
15.?Huang, C., Yang, Y., Wang, H., Xie, L., Wu, S., Xu, L., & Wu, F. 2022. In-run measuring 177Hf16O/177Hf as a routine technique for in-situ Hf isotopic compositions analysis in zirconium-bearing minerals by laser ablation MC-ICP-MS.?Spectrochimica Acta Part B: Atomic Spectroscopy, 194, 106486.
16.?Huang, C., Wang, H., Xie, L., Nie, N. X., Yang, Y., Zhao, X., & Yang, J. 2022. In situ Ti isotopic analysis by femtosecond laser ablation MC-ICP-MS. Journal of Analytical Atomic Spectrometry,?37, 2165-2175.
2021
17.?Wu S., Yang Y., Jochum K.P., Romer R.L., Glodny J., Savov I.P., Agostini S., De Hoog J.C.M., Peters S.T.M., Kronz A., Zhang C., Bao Z., Wang X., Li Y., Tang G., Feng L., Yu H., Li Z., Le Z., Lin J., Zeng Y., Xu C., Wang Y., Cui Z., Deng L., Xiao J., Liu Y., Xue D., Di Z., Jia L., Wang H., Xu L., Huang C., Xie L., Pack A., Worner G., He M., Li C., Yuan H., Huang F., Li Q., Yang J., Li X. and Wu F. 2021 Isotopic Compositions (Li-B-Si-O-Mg-Sr-Nd-Hf-Pb) and Fe2+/ΣFe Ratios of Three Synthetic Andesite Glass Reference Materials (ARM-1, ARM-2, ARM-3),?Geostandards and Geoanalytical Research, 45, 719–745.
18.?Huang C., Wang H., Yang J. H., Yang C., Li Z. X., Yang Y. H., Feng L. J., Xie L. W. and Wu S. T. 2021. Characterization of the potential reference material SA02 for micro-beam U–Pb geochronology and Hf–O isotopic composition analysis of zircon,?Journal of Analytical Atomic Spectrometry, 36, 368-374.
19.?Huang C., Wang H., Yu H. M. , Feng L. P., Xie L. W., Yang Y. H., Wu S. T., Xu L, Yang J. H. 2021. Further characterization of SA01 and SA02 zircon reference materials for Si and Zr isotopic compositions via femtosecond laser ablation MC-ICP-MS,?Journal of Analytical Atomic Spectrometry, 36:2192-2201.
20.?Xu L., Zhang W., Luo T., Yang J. H., and Hu Z. C. 2021. In situ Fe isotopic analyses of fourteen reference materials using a synthetic Cr standard for mass bias and isobaric interference corrections by femtosecond LA-MC-ICP-MS,?Journal of Analytical Atomic Spectrometry, 36, 747-757.
21.?楊岳衡, 楊明, 王浩, 楊進(jìn)輝, 吳福元. 2021. 微區原位黑鎢礦U-Pb年代學(xué)方法及應用. 中國科學(xué) 地球科學(xué). 51: 171–174. Yang Y.H., Yang M., Wang H., Yang J.H., Wu F.Y. 2021. Methodology for in situ wolframite U-Pb dating and its application.?Science China Earth Science, 64: 187–190
2020?
22.?Yang M., Yang Y.H., Wu S.T., Rolf Romer, Che X.D., Zhao Z.F., Li W.S., Yang J.H., Wu F.Y., Xie L.W., Huang C. Zhang D. Zhang Y. 2020. Accurate and precise in situ U-Pb dating of wolframite series minerals via LA-SF-ICP-MS.?Journal of Analytical Atomic Spectrometry, 35, 2191–2203.
23.?Wu S.T., Yang M., Yang Y.H., Xie L.W., Huang C., Wang H., Yang J.H. 2020. Improved in situ zircon U–Pb dating at high spatial resolution (5–16 μm) by laser ablation–single collector–sector field–ICP–MS using Jet sample and X skimmer cones.?International Journal of Mass Spectrometry, 456, 116394.
24.?Wu S.T., Yang Y.H., Wang H., Huang C., Xie L.W., Yang J.H. 2020. Characteristic performance of guard electrode in LA–ICP–MS for multiple element quantification.?Atomic Spectroscopy, 41, 154–161.
25.?Wu S.T., Wu Y.D., Yang Y.H., Wang H., Huang C., Xie L.W., Yang J.H. 2020. Simultaneous quantification of forsterite content and minor–trace elements in olivine by LA–ICP–MS and geological applications in Emeishan large igneous province.?Minerals, 10, 634.
26.?Yang, Y.H., Yang, M., Jochum, K.P., Wu, S.T., Zhao, H., Xie, L.W., Huang, C., Zhan, X.C., Yang, J.H. Wu, F.Y. 2020. High-Precision Sr-Nd-Hf-Pb Isotopic Composition of Chinese Geological Standard Glasses CGSG-1, CGSG-2, CGSG-4 and CGSG-5 Reference Materials by MC-ICP-MS and TIMS.?Geostandards and Geoanalytical Research. 44,567-579.
27.?Yang, M., Yang, Y.H.,* Evans N.J., Xie, L.W., Huang, C., Wu, S.T., Yang, J.H. Wu, F.Y. 2020. Precise and Accurate Determination of Lu and Hf Contents and Hf Isotopic Compositions in Chinese Rock Reference Materials by MC-ICP-MS.?Geostandards and Geoanalytical Research. 44, 543-565.
28.?Huang C., Wang H., Yang J.H., Ramezani J., Yang C., Zhang S.B., Yang Y.H., Xia X.P., Feng L.J., Lin J., Wang T.T., Ma Q., He H.Y., Xie L.W., Wu S.T. 2020. SA01-A new potential zircon reference material for micro-beam U-Pb age and Hf-O isotopic analysis.?Geostandards and Geoanalytical Research. 44(1), 103-123.
29.?Huang, C. Yang, Y.H., Xie, L.W., Wu, S. T., Wang, H. Yang J. H. and Wu, F. Y. 2020. In situ sequential U-Pb age and Sm-Nd systematics measurement of natural LREE-enriched minerals using single laser ablation multi-collector inductively coupled plasma mass spectrometry.?Journal of Analytical Atomic Spectrometry, 25(3), 510-517.
30.?Xu L., Yang J.H., Zeng Q.D., Xie L.W., Zhu Y.S., Li R. and Li B. 2020. Pyrite Rb-Sr, Sm-Nd and Fe isotopic constraints on the age and genesis of the Qingchengzi Pb-Zn deposits, northeastern China.?Ore Geology Reviews, 117, 103324.
31.?Wei Q.D., Wang H., Yang Y.H., Yang J.H., Huang C., Wu S.T., Xie L.W. 2020. KV01 zircon—A potential New Archean reference material for microbeam U-Pb age and Hf-O isotope determinations.?Science China Earth Sciences, 63(11): 1780-1790
2019?
32.?Huang C. Wang H. Yang J.H., Xie L.W. Yang Y.H. Wu S.T. 2019. Further characterization of the BB zircon via SIMS and MC-ICP-MS for Li, O, and Hf isotopic compositions.?Minerals, 9, 774.
33.?Yang Y.H. Wu F.Y., Li Q.L, Rojas-Agramonte Y., Yang J.H., Li Y., Ma Q., Xie L.W., Huang C., Fan H.R., Zhao Z.F., Xu C. 2019.?In situ U-Th-Pb dating and Sr-Nd isotope analysis of bastn?site by LA-(MC)-ICP-MS.?Geostandards and Geoanalytical Research. 43(4), 543-565.
34.?Wu S. T., Worner G. Jochum K.P., Stoll B. Simon K., Kronz A. 2019. The preparation and preliminary characterization of three synthetic andesite reference glass materials (ARM-1, ARM-2, ARM-3) for in situ microanalysis.?Geostandards and Geoanalytical Research. 43(4), 567-584.
2018?
35.?Mei, Q. F., Yang, J. H., Yang, J. H. 2018. An improved extraction chromatographic purification of tungsten from a silicate matrix for high precision isotopic measurements using MC-ICPMS.?J. Anal. At. Spectrom., 33, 569–577.
36.?Yang, Y. H., Wu, F. Y., Yang, J. H., Mitchell, R. H., Zhao, Z. F., Xie, L. W., Huang, C., Ma, Q., Yang, M., Zhao, H. 2018. U-Pb age determination of schorlomite garnet laser ablation inductively coupled plasma mass spectrometry.?J. Anal. At.?Spectrom., 33: 231-239.
37.?Xie, L.W., Evans, N.J., Yang. Y.H., Huang, C. Yang, J. H. 2018. U-Th-Pb geochronology and simultaneous analysis of multiple isotope systems in geological samples by LA-MC-ICP-MS.?J. Anal. At.?Spectrom.,, 33, 1600-1615.
38.?Xie, L.W., Xu, L., Yin, Q.Z., Yang, Y.H., Huang, C. Yang, J.H. 2018. A novel sample cell for reducing the?“Position Effect”?in laser ablation MC-ICP-MS isotopic measurements.?J. Anal. At. Spectrom.,, 33, 1571–1578.
39.?Wu, S.T., Huang C. Xie L.W. Yang Y.H., Yang J.H. 2018. Iolite Based Bulk Normalization as 100% (m/m) Quantification Strategy for Reduction of Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Transient Signal.?Chinese Journal of Analytical Chemistry, 46, 1628-1636.
2017?
40.?Xie, L. W., Yang, J. H., Yin, Q. Z., Yang, Y. H., Liu, J. B., Huang, C. 2017. High spatial resolution in situ U–Pb dating using laser ablation multiple ion counting inductively coupled plasma mass spectrometry (LA-MIC-ICP-MS).?J. Anal. At. Spectrom., 32, 975–986.
2016?
41.?李楊,?楊岳衡,?焦淑娟,?吳福元,?楊進(jìn)輝,?謝烈文,?黃超. 2016.?金紅石Hf同位素激光原位多接收等離子體質(zhì)譜（LA-MC-ICP-MS）測定.?中國科學(xué)D?地球科學(xué). 46: 857-869. Li, Y., Yang, Y. H., Jiao, S.J., Wu, F. Y., Yang, J. H., Xie, L.W., Huang, C. 2015. In situ determination of hafnium isotopes from rutile using LA-MC-ICP-MS.?Science in China, Series D. 58: 2134-2144.
2015?
42.?Huang, C., Yang, Y. H., Yang, J. H., Xie, L. W. 2015. In situ simultaneous measurement of Rb-Sr/Sm-Nd or Sm-Nd/Lu-Hf isotopes in natural minerals by using laser ablation multi-collector ICP-MS.?J. Anal. Atom. Spectrom., 30: 994-1000.
2014?
43.?Yang, Y. H., Wu, F. Y., Yang, J. H., David, M. C., Xie, L. W., Chu, Z. Y., Zhang, Y. B., Huang, C. 2014. Sr and Nd isotopic compositions of apatite reference materials used in U-Th-Pb geochronology.?Chem. Geol. 385: 35-55.
44.?Yang, Y. H., Wu, F. Y., Xie, L. W., Chu, Z. Y., Yang, J. H. 2014. Reinvestigation of doubly charged ion of heavy rare earth elements interferences on Sr isotopic analysis using multi-collector inductively coupled plasma mass spectrometry.?Spectrometry Acta (B)?97: 118-123.
45.?Yang, Y. H., Wu, F. Y., Li, Y., Yang, J. H., Xie, L. W., Liu, Y., Zhang, Y. B., Huang, C. 2014. In situ U-Pb dating of bastnaesite by LA-ICP-MS.?J. Anal. Atom. Spectrom., 29: 1017-1023.
2013?
46.?Yang, Y. H., Wu, F. Y., Chu, Z. Y., Xie, L. W., Yang, J. H. 2013. High-precision simultaneous determination of 147Sm/144Nd and 143Nd/144Nd ratios in Sm–Nd mixtures using multi-collector inductively coupled plasma mass spectrometry and its comparison to isotope dilution analysis.?Spectrometry Acta (B), 79/80: 82-87.
2012?
47.?孫金鳳,?楊進(jìn)輝,?吳福元,?謝烈文,?楊岳衡,?劉志超,?李獻華. 2012.?榍石原位微區LA-ICPMS U-Pb年齡測定.?科學(xué)通報, 57: 1603-1615. Sun, J. F., Yang, J. H., Wu, F. Y., Xie, L. W., Yang, Y. H., Liu, Z. C., Li, X. H. 2011. In situ U-Pb dating of titanite by LA-ICPMS. Chinese Sci. Bull., 57: 2506-2516.
48.?Yang, Y.H., Wu, F.Y., Liu Z.C., Chu, Z.Y., Xie, L.W., Yang, J.H. 2012. Evaluation of Sr chemical purification technique for natural geological samples using common cation-exchange and Sr-specific extration chromatographic resin prior to MC-ICP-MS or TIMS measurement.?J. Anal. Atom. Spectrom., 27: 516-522.
49.?Liu Z. C., Wu, F. Y., Yang, Y. H., Yang, J. H., Wilde, S.A. 2012. Neodymium isotopic compositions of the standard monazites used in U–Th–Pb geochronology. Chemical Geology, 334, 221-239.
2011?
50.?劉志超,?吳福元,?郭春麗,?趙子福,?楊進(jìn)輝,?孫金鳳. 2011.?磷釔礦U-Pb年齡激光原位ICP-MS測定.?科學(xué)通報, 56: 2772-2781. Liu, Z.C., Wu, F. Y., Guo, C. L., Zhao, Z. F., Yang, J. H., Sun, J. F. 2011. In situ U-Pb dating of xenotime by laser ablation (LA)-ICP-MS.?Chinese Sci. Bull., 56: 2948-2956.
51.?Xie, L. W., Yang, J. H., Wu, F. Y., Yang, Y. H., Wilde, S. A. 2011. PbSL dating of garnet and staurolite: constraints on the Paleoproterozoic crustal evolution of the eastern block, North China Craton.?J. Asian Earth Sci., 42: 142-154.
52.?Xie, L. W., Yin, Q. Z., Yang, J. H., Wu, F. Y., Yang, Y. H. 2011. High precision analysis of Mg isotopic composition in olivine by laser ablation MC-ICP-MS.?J. Ana. Atom. Spectrom., 26: 1773-1780.
53.?Yang, Y. H., Wu, F. Y., Wilde, S. A., Xie, L. W. 2011. A straightforward protocol for Hf purification by single step anion-exchange chromatography and isotopic analysis by MC-ICP-MS applied to geological reference materials and zircon standards. Inter.?J. Mass.?Spectrom., 299: 47-52.
54.?Yang, Y. H., Chu, Z. Y., Wu, F. Y., Xie, L. W., Yang, J. H. 2011. Precise and accurate determination of Sm, Nd concentrations and Nd isotopic compositions in geological samples by MC-ICP-MS.?J. Anal. Atom. Spectrom., 26: 1237-1244.
55.?Yang, Y. H., Wu, F. Y., Xie, L. W., Yang, J. H., Zhang, Y. B. 2011. High-precision direct determination of the 87Sr/86Sr isotope ratio of bottled Sr-rich natural mineral drinking water using multiple collector inductively coupled plasma mass spectrometry.?Spectrochim. Acta (B),?66: 656-660.
2010?
56.?Wu, F. Y., Yang, Y. H., Marks, M. A. W., Liu, Z. C., Zhou, Q., Ge, W. C., Yang, J. S., Zhao, Z. F., Mitchell, R. H., Markl, G. 2010. In situ U–Pb, Sr, Nd, and Hf isotopic analysis of eudialyte by LA–(MC)?–ICP–MS.?Chem. Geol.,?273: 8-34.
57.?Wu, F. Y., Yang, Y. H., Mitchell, R. H., Bellatreccia, F., Li, Q. L., Zhao, Z. F. 2010. In situ U–Pb and Nd-Hf-(Sr) isotopic investigations of zirconolite and calzirtite.?Chem. Geol.,?277: 178-195.
58.?Yang Y. H., Wu F. Y., Xie L. W., Zhang Y. B. 2010. High-precision measurements of the 143Nd/144Nd isotope ratio in certified reference materials without Nd and Sm separation by multiple collector inductively coupled plasma mass spectrometry.?Anal. Lett.,?43: 142-150.
59.?Yang Y. H., Zhang H. F., Chu Z. Y., Xie L. W., Wu F. Y. 2010. Combined chemical separation of Lu, Hf, Rb, Sr, Sm and Nd from a single rock digest and precise and accurate isotope determinations of Lu-Hf, Rb-Sr and Sm-Nd isotope systematics using Multi-Collecter ICP-MS and TIMS. Inter.?J. Mass Spectro.,?290: 120-126.
2009?
60.?Yang, Y. H., Wu, F. Y., Wilde, S. A., Liu, X. M., Zhang, Y. B., Xie, L. W., Yang, J. H., 2009. In-situ perovskite Sr-Nd isotopic constraints on petrogenesis of the Mengyin kimberlites in the North China Craton.?Chem. Geol.,?264: 24-42.
61.?楊岳衡,?吳福元,?謝烈文,?張艷斌,?楊進(jìn)輝. 2009.?地質(zhì)樣品Sr同位素激光原位等離子體質(zhì)譜?(LA-MC-ICPMS)測定.?巖石學(xué)報, 25: 3431-3441.
2008?
62.?謝烈文,?張艷斌,?張輝煌,?孫金鳳,?吳福元. 2008.?鋯石/斜鋯石U-Pb和Lu-Hf同位素以及微量元素成分的同時(shí)原位測定.?科學(xué)通報, 53: 220-228. Xie, L. W., Zhang, Y. B., Zhang, H. H., Sun, J. F., Wu, F. Y., 2008. In situ simultaneous determination of trace elements, U-Pb and Lu-Hf isotopes in zircon and baddeleyite.?Chinese Sci. Bull.,?53: 1565-1573.
63.?楊岳衡,?孫金鳳,?謝烈文,?范宏瑞,?吳福元. 2008.?地質(zhì)樣品Nd同位素激光原位測定.?科學(xué)通報, 53, 568-576. Yang, Y. H., Sun, J. F., Xie, L. W., Fan, H. R., Wu, F. Y. 2008. In situ Nd isotopic measurement of geological samples by laser ablation.?Chinese Sci. Bull.,?53: 1062-1070.
2007?
64.?Yang, J. H., Wu, F. Y., Wilde, S. A., Xie, L. W., Yang, Y. H., Liu, X. M., 2007. Tracing magma mixing in granite genesis: in situ U-Pb dating and Hf-isotope analysis of zircons. Contrib.?Mineral. Petrol.,?153(2): 177-190.
65.?楊岳衡,?張宏福,?謝烈文,?吳福元. 2007.?多接收器電感耦合等離子質(zhì)譜精確測定釹同位素組成.?分析化學(xué), 35: 71-74. Yang, Y. H., Zhang, H. F., Xie, L. W., Wu, F. Y. 2007. Accurate measurement of neodymium isotopic composition using Neptune multiple collector inductively coupled plasma mass spectrometry.?Chinese J. Anal. Chem., 35: 71-74.
66.?楊岳衡,?張宏福,?劉穎,?謝烈文,祁昌實(shí),?涂湘林. 2007.?巖石樣品的一次陰離子交換Hf分離及其MC-ICP-MS測試.?巖石學(xué)報?23: 227-232.
2006?
67.?Wu, F. Y., Yang, Y. H., Xie, L. W., Yang, J. H., Xu, P. 2006. Hf isotopic compositions of the standard zircons and baddeleyites used in U-Pb geochronology.?Chem. Geol., 234: 105-126.
2004?
68.?徐平,?吳福元,?謝烈文,?楊岳衡. 2004. U-Pb同位素定年標準鋯石的Hf同位素.?科學(xué)通報, 49: 1403-1410. Xu, P., Wu, F. Y., Xie, L. W., Yang, Y. H., 2004. Hf isotopic compositions of the standard zircons for U-Pb dating. Chinese?Sci. Bull., 49: 1642-1648.
專(zhuān)利?
2023
1.?Wu S. ?et al. METHOD FOR SIMULTANEOUSLY MEASURING THE VALUE OF FORSTERITE AND TRACE ELEMENTS IN OLIVINE 2023?Unite States,?Patient No: US 11,664,208 B2
2.?吳石頭?等.?一種原位微區磷灰石Lu-Hf定年方法?中國?ZL 2023 1 0028497.7. 授權公告日：2023.08.23
3.?吳石頭?等. 一種原位微區石榴石Lu-Hf定年方法?中國?ZL 202310045795.7. 授權公告日：2023.08.18
4.?吳石頭?等. 一種原位微區磷釔礦Lu-Hf定年方法?中國?ZL 2023 1 0028565.X. 授權公告日：2023.06.16
2022
5.?吳石頭. 一種原位微區方解石U-Pb定年方法 中國. ZL 2021 1 0891559.8. 授權公告日：2022.10.09
2021
6.?吳石頭,?吳亞?wèn)|,?楊岳衡,?王浩,?黃超,?謝烈文.?一種同時(shí)測定橄欖石中的鎂橄欖石值和微量元素方法?中國. ZL 2020 1 0404435.8. 2021.04.09?
7.?黃超，《一種物質(zhì)分析方法、裝置和靜電離子阱質(zhì)量分析器》，ZL202010535945.9,? 2021.10.29?
8.?黃超，《一種鋯石鉿同位素的檢測方法》，ZL202010974890.1,? 2021.08.24?
2020?
9.?楊岳衡，《一種無(wú)需稀釋劑的地質(zhì)樣品釤-釹同位素同時(shí)測試的方法》，ZL201910791476.4，2020.07.10.
2019?
10.?謝烈文，楊進(jìn)輝，楊岳衡，劉景波，黃超，《一種測定鋯石樣品的鈾鉛年齡的方法》，?ZL201710124041.5，2019.03.03.
11.?謝烈文，《一種均勻氣流激光剝蝕池及其應用》，ZL201711434961.3，2019.07.02.
12.?楊岳衡，馬倩，儲著(zhù)銀，謝烈文，黃超，楊進(jìn)輝，《一種镥-鉿同位素質(zhì)譜測試的方法》，?ZL201810174335.3，2019.05.24.
2017?
13.?黃超；謝烈文；楊岳衡，《一種激光同步雙剝蝕系統及其剝蝕方法》，ZL201711126032.6, 2017.11.15
2015?
14.?黃超，《一種實(shí)現電感耦合等離子體離子源工作在惰性氣體環(huán)境的方法及裝置》，ZL201510813422.5, 2015.11.23
2013?
15.?黃超,《一種實(shí)現質(zhì)譜分析系統中獨立儀器聯(lián)動(dòng)的系統和方法》，ZL201310299108.0，2013.07.17
16.?黃超,《一種惰性氣體磁式質(zhì)譜儀及設計方法》，ZL201310299609.9，2013.07.17
用戶(hù)須知：
歡迎國內外學(xué)者來(lái)實(shí)驗室開(kāi)展分析與合作研究！用戶(hù)填寫(xiě)“MC實(shí)驗室_實(shí)驗測試預約登記表”（見(jiàn)附件），提交至mclab@mail.iggcas.ac.cn信箱，審核通過(guò)后通知具體的實(shí)驗時(shí)間
附件：實(shí)驗測試預約登記表
附件：規范的分析方法描述
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測試項目 |
所內收費 |
所外收費 |
備注：所有實(shí)驗過(guò)程均由自己完成 | ||
|
按時(shí)間 |
按點(diǎn)數 |
按時(shí)間 |
按點(diǎn)數 | ||
|
礦物微量元素 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
薄片或樹(shù)脂靶 |
|
鋯石U-Pb年齡 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
樹(shù)脂靶 |
|
榍石U-Pb年齡 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
薄片或樹(shù)脂靶 |
|
獨居石U-Pb年齡 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
薄片或樹(shù)脂靶 |
|
磷釔礦U-Pb年齡 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
薄片或樹(shù)脂靶 |
|
鈮鉭礦U-Pb年齡 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
薄片或樹(shù)脂靶 |
|
氟碳鈰礦U-Pb年齡 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
薄片或樹(shù)脂靶 |
|
石榴石U-Pb年齡 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
薄片或樹(shù)脂靶 |
|
黑鎢礦U-Pb年齡 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
薄片或樹(shù)脂靶 |
|
錫石U-Pb年齡 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
薄片或樹(shù)脂靶 |
|
符山石U-Pb年齡 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
薄片或樹(shù)脂靶 |
|
褐簾石U-Pb年齡 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
薄片或樹(shù)脂靶 |
|
方解石U-Pb年齡 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
薄片或樹(shù)脂靶 |
|
鋯石Hf同位素 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
樹(shù)脂靶 |
|
礦物Sr同位素 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
建議先作礦物微量(提前激光測試微量，Sr含量大于1000ppm，且Er/Sr或Yb/Sr小于0.1才適合激光Sr同位素) |
|
礦物Nd同位素 |
1200元/小時(shí) |
150元/點(diǎn) |
1500元/小時(shí) |
200元/點(diǎn) |
建議先作礦物微量(提前激光測試微量，Nd含量大于1000ppm) |
收費標準自2022年10月1日起施行
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實(shí)驗室電話(huà)：010-8299 8671。
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